C03: Atmospheric composition and ocean colour of the Arctic retrieved from satellite measurements
PIs: John P. Burrows, Astrid Bracher
The Arctic cryosphere and ocean have a unique role in the Earth’s radiation budget and the bio–geochemical cycling in the planetary boundary layer. Although conventionally the Arctic is considered pristine, it is increasingly being influenced by anthropogenic activity. Our understanding of the impact of the observed decline of sea ice on the atmospheric composition, in particular in the Atmospheric Boundary Layer (ABL), the interactions with ice, snow and ocean and the ecosystems and related feedback is limited and inadequate. Changes in the extent and type of sea ice, and thus amount of open ocean water, influence the inorganic production of halogen oxides and the productivity of the biomass in the ocean. The halogen free radicals play a key role in the oxidizing capacity of the Arctic ABL through complex inorganic and organic heterogeneous reactions and/or bio–geochemical photochemical mechanisms. The amount and type of phytoplankton and Coloured Dissolved Organic Matter (CDOM) are also influenced by the changing amount of ice. They are sources of organo–halogens released from the surface ocean to the atmosphere. The oxidation and photolysis of organo–halogens generate halogen radicals. Thus the amounts and distributions of halogen radicals and oxidation chemistry in the Arctic, are also expected to respond to Arctic Amplification. Further the absorption by chlorophyll and its pigments warms the ocean and photosynthesis by phytoplankton draws down carbon dioxide.
The changes and links between reactive halogens and phytoplankton and their response to changing physical conditions (sea ice coverage and thickness, which depend on its age, temperature, stratification, radiation, etc. of the surface ocean and ABL) are the research foci of this investigation. To meet the objectives of the project, consistent and consolidated data products, retrieved from remote sensing instrumentation on satellite platforms, will be produced and studied to provide insight about the changes of trace constituents and phytoplankton types and CDOM absorption over the past two decades. The scientific objectives of this proposal are:
- To produce validated data sets using observations from the satellite instruments GOMEc, SCIAMACHYand GOME–2 and merged products on (i) the distribution of phytoplankton types and CDOM absorption in the Arctic Ocean, and (ii) halogen oxides (BrO and IO) in the Arctic, primarily in the troposphere but also in the stratosphere
- To evaluate changes in the quantities of halogen amounts, phytoplankton types and CDOM over the last two decades and thereby to establish, investigate and understand the changes in the oxidative capacity of the Arctic ABL,
- To assess the impact of Arctic Amplification and the related changing coverage and thickness of sea ice, (increasing) temperatures, solar radiation on the phytoplankton composition, loading of CDOM and halogen chemistry of the ABL in the Arctic region, their changes and the feedback between each other.
This project utilizes, in the first instance, the long–term remote sensing measurements of the upwelling radiation at the top of the atmosphere in the solar spectral region. The series of hyperspectral measurements of UV, visible and near infrared radiation began in 1995 with the instrument GOME (ESA ERS–2 1995 to 2003), and has been continued with SCIAMACHY (ESA Envisat 2002 to 2012) and GOME–2 (MetOp–A 2006 to present MetOp–B 2012 to present). These instruments fly in sun synchronous orbits, having equator crossing times in the early morning. Data from the OMI instrument on AURA, (2004 until today) and TROPOMI in Sentinel-5-P (launched in 2016), which provide higher spatial resolution in a sun synchronous early afternoon orbit, will also be used for halogen oxide and ocean colour retrievals. In addition, multi spectral measurements of the upwelling solar radiation having much higher spatial resolution but much lower spectral resolution are available from the sensors ATRS–2 (ERS–2 1995 to 2003), MERIS and AATSR (both on Envisat 2002 to 2012 ), SeaWiFS (on OrbView–2 1997 to 2007), MODIS (on Aqua 2000 to present), AVHRR–3 (MetOp–A 2006 to present and MetOp–B 2012 to present) and OLCI (Sentinel–3 planned for launch in 2016). Data from these instruments will also be used to complement the hyperspectral retrieval results and validate ocean–ice–ecosystem system model data.
Hypothesis: Arctic Amplification impacts significantly on both, oceanic phytoplankton amount and types, and the Arctic ABL chemical composition.
Central questions which will be answered in the project are:
- What are the recent decadal changes in Arctic atmospheric composition and oceanic phytoplanktonand coloured dissolved organic matter (CDOM) composition, and
- How are they linked to each other and to changes of sea ice and other environmental and meteorologicalparameters?
Role within (AC)³
- Key atmospheric constitutents in the ABL and absorbers of radiation in the surface ocean, and their interactions to be used as input for Cluster D and E modelling
- Surface properties and radiative forcing needed to improve retrievals and models, respectively
Prof. Dr. John P. Burrows
University of Bremen
Institute of Environmental Physics
Prof. Dr. Astrid Bracher
Alfred-Wegener-Insitute Helmholtz Center for Polar and Marine Research (AWI)
Dr. Anne Blechschmidt
University of Bremen
Institute of Environmental Physics
Zeppenfeld, S., M. van Pinxteren, M. Hartmann, A. Bracher, F. Stratmann, and H. Herrmann, 2019: Glucose as a potential chemical marker for ice nucleating activity in Arctic seawater and melt pond samples, accepted for publication in Environmental Science & Technology
Álvarez, E., S. Thoms, A. Bracher, Y. Liu, and C. Völker, 2019: Prediction of photo-protective carotenoids at global scale, accepted by Global Biogeochemical Cycles, doi.org/10.1029/2018GB006101
Fernandez, R.P., A. Carmona-Balea, C.A. Cuevas, J.A. Barrera, D.E. Kinnison, J.-F. Lamarque, C. Blaszczak-Boxe, K. Kim, W. Choi, T. Hay, A.-M. Blechschmidt, A. Schönhardt, J.P. Burrows, and A. Saiz-Lopez, 2019: Modeling the Sources and Chemistry of Polar Tropospheric Halogens (Cl, Br, I) using the CAM-Chem Global Chemistry-Climate Model, accepted for publication in J. Adv. Model Earth Sy., doi:10.1029/2019MS001655
Seo, S., A. Richter, A.-M. Blechschmidt, I. Bougoudis, and J.P. Burrows, 2019: First high resolution BrO column retrievals from TROPOMI, Atmos. Meas. Tech., 12, 2913-2932, doi:10.5194/amt-12-2913-2019
Soppa, M.A., V. Pefanis, S. Hellmann, S.N. Losa, J. Hölemann, M.A. Janout, F. Martynov, B. Heim, T. Dinter, V. Rozanov, and A. Bracher, 2019: Assessing the Influence of Water Constituents on the Radiative Heating of Laptev Sea Shelf Waters, Frontiers in Marine Science, 6, Article 221, doi:10.3389/fmars.2019.00221
Oelker, J., A. Richter, T. Dinter, V.V. Rozanov, J.P. Burrows, and A. Bracher, 2019: Global diffuse attenuation coefficient derived from vibrational Raman scattering detected in hyperspectral backscattered satellite spectra, Optics Express, 27, 2, A829-A855, doi:10.1364/OE.27.00A829
Engel A., A. Bracher, T. Dinter, S. Endres, J. Grosse, K. Metfies, I. Peeken, J. Piontek, I. Salter, E.-M. Nöthig, 2019: Inter-annual variability of organic carbon concentrations across the Fram Strait (Arctic Ocean) during summer 2009 -2017, Frontiers in Marine Science. section Global Change and the Future Ocean, 6, 187, doi:10.3389/fmars.2019.00187
Liu, Y., E. Boss, A.P. Chase, H. Xi, X. Zhang, R. Röttgers, Y. Pan, and A. Bracher, 2019: Retrieval of phytoplankton pigments and functional types from underway spectrophotometry in the Fram Strait, Remote Sensing, 11(3), 318, doi:10.3390/rs11030318
Pradhan H.K., C. Völker, S.N. Losa, A. Bracher, L. Nerger, 2019: Assimilation of global total chlorophyll OC-CCI data and its impact on individual phytoplankton fields, Journal of Geophysical Research Oceans, doi:10.1029/2018JC014329
Liu. Y., Roettgers R., Ramírez-Pérez M., Dinter T., Steinmetz F., Noethig E.-M., Hellmann S., Wiegmann S., Bracher A., 2018: Underway spectrophotometry in the Fram Strait (European Arctic Ocean): a highly resolved chlorophyll a data source for complementing satellite ocean color, Optics Express, 26, 14, A678, doi:10.1364/OE.26.00A678.
Data supplement is available here.
Losa S., Soppa M. A., Dinter T., Wolanin A., Brewin R. J. W., Bricaud A., Oelker J., Peeken I., Gentili B., Rozanov. V. V., Bracher A., 2017: Synergistic exploitation of hyper- and multispectral precursor Sentinel measurements to determine Phytoplankton Functional Types at best spatial and temporal resolution (SynSenPFT), Front. Mar. Sci., 4:203, doi:10.3389/fmars.2017.00203
Data supplement is available here.
Rozanov V.V., T. Dinter, A.V. Rozanov, A. Wolanin, A. Bracher, Burrows J.P., 2017: Radiative transfer modeling through terrestrial atmosphere and ocean accounting for inelastic scattering processes: Software package SCIATRAN. J. Quant. Spectrosc. Rad. Transfer, 194, 65-85, doi:10.1016/j.jqsrt.2017.03.009
Space based observation of volcanic iodine monoxide, Atmos. Chem. Phys., 17, 4857-4870,2017:
Blechschmidt, A.-M., Richter, A.,Burrows, J. P., Kaleschke, L., Strong, K., Theys, N., Weber, M., Zhao, X., and Zien, A., 2016: An exemplary case of a bromine explosion event linked to cyclone development in the Arctic, Atmos. Chem. Phys.,16, 1773-1788, doi:10.5194/acp-16-1773-2016